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Material Safety Data Sheet

1.Chemical Product and Company Information

Product      

Anti-Rust Spray (Iron) 20 ml AWI-95

Company   

Air Water Sol Inc.

Address

2-16-2 Iwamoto-cho, Kanda MC Bldg., Chiyoda-Ku Tokyo Japan (Main Office)
817-1 Sanga, Minori-cho, Ibaragi-gun, Ibaragi Japan  (Research Center)

Department

Research and Development Dept.

Telephone

03-5835-3900  (Main Office)   0299-48-4402  (Research Center)

Fax

03-5835-3908  (Main Office)   0299-48-4401  (Research Center)

 

In case of emergency, please call Research and Development Dept. at Research Center.


2.Composition/Information on Ingredients (a mixture, listed hazardous and toxic substances)

Ingredients

CAS No.

PRTR*

ISHL*
(Reg. No.)

Content
(Weight %)

Lubricant & base oil

--

NA

NA

5~15

Mineral spirits (Fluid Paraffin)

64742-88-7

NA

No. 549

30~40

Other elements (additives, etc.)

--

NA

NA

5~15

Liquefied Petroleum Gas

Propane

74-98-6

NA

NA

5~15

i-Butane

75-28-5

NA

NA

5~15

n-Butane

106-97-8

NA

No. 480

25~35

*CAS: Chemical Abstracts Service Registry Number
*PRTR: Pollutant Release & Transfer Register
*ISHL: Industrial Safety and Health Law


3.Summary of Toxicity and Hazards

Most Acute Toxicity & Hazards

*Hazardous substance as Class 4 & Class 2 Petroleum products under Fire Service Law. There is a possibility of explosion if residual vapor accumulates.

Classification

*High pressured gas (combustible gas)
*Flammable liquid

Hazards

*Combustible gas inside. Danger of rupture due to rise in internal pressure caused by ignition or high temperature.

 

*Danger of possible explosion due to residual vapor.

Toxicity

*Can cause irritation of eyes, skin and respiratory tracks. Danger of inflammation with repeated contact,


4.First Aid Measures

Contact with Eyes

*Wash immediately for at least 15 minutes with a large amount of clean water. Alternatively, use boric acid solution and continue washing with clean water for a long period of time.

 

*Immediate treatment by a medical specialist.

Contact with Skin

*Quickly wipe the contact area with a cloth.

 

*Wash sufficiently with water, soap or a cleansing lotion for skin use.

 

  Do not use solvents or thinners.

 

*If an external change is noticed or there is pain, have a treatment by a medical specialist.

Inhalation

*When a large quantity of gas or vapor is inhaled, the affected person should be moved to a location with fresh air, keeping him warm and calm. If breathing is irregular or stops, conduct the artificial respiration.

 

*Do not let him swallow vomit.

 

*If a person feels bad after inhaling gas, keep him calm where there is fresh air, and have him treated by a medical specialist.

Ingestion

*If ingested by mistake, keep the patient calm and have him treated by a medical specialist.

 

*Do not let him swallow vomit.

 

*Do not let him cough excessively unless directed by a medical specialist.

5.Fire Fighting Measures

Extinguishing Media

*Type ABC or BC powder fire extinguishers, Carbon dioxide, Foam or Sand

Extinguishing Methods

*Undertake the fire extinguishing from upwind. Those engaged in the fire extinguishing should wear suitable protective gears (fireproof clothing and eye protection) and use breathing apparatus.

 

*Quickly remove all combustible materials from the area.

 

*Used designated extinguishers.

 

*If aerosol containers are present, there is a danger of rupture. When engaged in fire fighting, persons should keep a sufficient distance away, and containers exposed to heat should be cooled with water.


6.Accidental Release Measures

Personal

*To prevent exposure, proper protective gears should be worn during work.

Precautions

*If leak occurs (a gush out), the measures should be taken from upwind, and the leaking part of the container should be turned to upward to let all gas gush out before taking the measures.

 

*Sources of combustion and high temperature items in the vicinity should be removed immediately, and people should take refuge upwind.

 

Only authorized personnel should be allowed in the area.

 

*Suitable fire extinguishers should be prepared in case of a fire brake.
*If large amount of vapor arises, the generation of the vapor should be held down by spraying with water.

Environment
Precautions &
Removal Methods

*The leaked liquid should not be discharged into the sewer or the gutter.
*The leaked liquid should be collected in a sealed container, and the residual liquid should be absorbed with sand or an inert absorbent and moved to a safe location.
*The leaked liquid should be collected using a device made of materials which will not generate sparks though an impact or static electricity.
*For small leakage, use sand or similar materials to absorb the liquid or use collecting agents.
*For large leakage, the flow should be prevented by surrounding it with earth, and leading the liquid to a safe location for the collection.


7.Handling and Storage (work is to be conducted in accordance with the pertinent regulations)

Handling

Technical Measures

*When the product used, the wind should be blow behind the person using the product so that the product does not come in direct contact with the person.

 

*It should be handled in well ventilated areas.

 

*Fire, sparks and high temperature items are not allowed to be used in the vicinity.

 

*The product should not be sprayed in the direction of a fire.

 

*If placed in areas where the temperature rises high, there is a danger of container rupture.

 

*Suitable protective gears should be worn to prevent contact with skin, mucus or clothing, and inhalation or entering eyes.

Precautions

*For work in enclosed areas, the work should be done with the sufficient ventilator should be installed and the person should wear suitable protective gears.

 

*After handling, hands should be washed thoroughly, and if the product sticks to the clothing, the cloth should be changed.

 

*Measures are to be take against static electricity, and anti-static material should be used for clothes and work shoes.

Safe Handling Advice

*Work should be done while wearing protective gears to prevent exposure to leakage.  Avoid inhalation of vapor and contact with skin.

 

 

Storage

 

Suitable Storage

*Store in a place where children cannot reach.

Conditions

*Avoid direct sunlight and provide good ventilation.

 

*Because of a possibility of leak or gush out due to corrosion of the container, avoid storing in humid places, such as kitchen and bathroom.

 

*Store away from fire or source of heat.

 

*Do not store in areas where the temperature rises above 40℃.

 

*Fire regulations, labor & health regulations and other regulations should be observed.


8.Exposure Control and Personal Protection

Place of Use

*There should be no source of high temperature or fire to where the product is used.

 

*When work is carried out in enclosed areas, a ventilator should also be used.


Name of Material

Controlled Concentration (ppm)

ACGIH (ppm)

ACGIH (mg/m3)

Lubricant & base oil

No data

No data

No data

Mineral spirits

No data

100 pm

--

Others (additives, etc.)

No data

No data

No data

Liquefied Petroleum Gas

Not established

Not established

Not established


Protective Gears

 

Breathing

*Antitoxin for organic gas, anti-dust mask, air mask for use in enclosed areas

Hands

*Gloves made of material which does not permit penetration of organic solutions and chemicals.

Eyes

*Protective glasses

Skin and Body

*Working clothes, safety work shoes

Suitable Hygienic Practices

*No smoking, eating and drinking while working.


9.Physical and Chemical Properties

Physical State

Main Ingredient

Liquefied Petroleum Gas

State

Liquid

Gaseous state under normal pressure, Liquid state in a pressurized container

Color

Brownish, semitransparent

No color, transparent

Odor

A small unique odor

Odorless

Specific temperature or temperature range whereby the physical state changes.

Boiling Point / Range

--

-42.1~-0.5℃

Flash Point / Range

Above 21℃

-104.4~-73.8℃

Ignition Point / Range

--

405~550℃

Vapor Pressure

--

0.54MPa

Density

About 0.83 (15℃)

0.53 (20℃)

Dissolvability

Does not dissolves in water

Dissolves slightly in water

10.Stability and Reactivity

Stability

*When the temperature reaching above 40℃, there is a danger of rupture.

 

*Pressure in a container at room temperature is about 0.40MPa.

Conditions to Avoid

*Storage in areas of high temperature and humidity or use near fire.

Hazardous Decomposition Products

*None in particular


11.Toxicological Information

*Lubricant & base oil, others (additives, etc.)

Irritation (skin, eyes)

: No useful information as of this time

Sensitizing potential

: No useful information as of this time

Acute toxicity

: No useful information as of this time

Semi-acute toxicity

: No useful information as of this time

Chronic toxicity

: No useful information as of this time

Source of Cancer

: No useful information as of this time

Source of Mutation

: No useful information as of this time

Reproductive toxicity

: No useful information as of this time

Teratogenesis

: No useful information as of this time

 

 

*Liquefied Petroleum Gas

: As of this time there are no reports on specific hazards.

 

 

*Product hazard

: No tests are being conducted concerning safety as a product.


12.Ecological Information

*Lubricant & basic oil, etc.

: No tests are being conducted on the effects for the environment as a product.

*Liquefied Petroleum Gas

: Low pollutant fuel


13.Disposal Considerations

Residual Waste

*When disposing, the gas should be discharged completely before handling.

 

*The liquid remain after the safe discharge of the gas should be entrusted to authorized disposal companies, or;

 

make a hole in the container and let the liquid absorbed in diatom earth and burn the earth in an open type incinerator little by little.

 

*Waste water used to wash the container and mechanical equipment should not be allowed to flow on the ground surface or into gutters.

Contaminated Containers and Packing

*To be separately disposed of after the content has been completely used.


14.Transport Information

Specific Transport Safety Measures

*When being transported, the container temperature should be maintained under 40℃, and the container should be loaded in the ways that there are no tumbling, no falling and no damaging. Prevention of cargo collapse should be firmly undertaken.

Land Transport

*Transport in accordance with Fire Service Law and other regulations.

Sea Transport

*Transport in accordance with Ship Safety Law.

Air Transport

*Transport in accordance with Civil Aeronautics Law.

UN Classification and
UN Number

Class 2  1950


15.Regulatory Information

High Pressure Gas Safety Law

:Not applicable (liquefied gas, combustible gas)

Ship Safety Law

:Hazardous materials (high pressured gas), flammable liquid

Civil Aeronautics Law

:High pressured gas, flammable liquid

Fire Service Law

:Hazardous type 4 class 2 petroleum, hazard level III

Industrial Safety and Health Law

:Combustible gas, flammable materials

Poisonous and Deleterious Substance Control Law

:Contains no designated substances.


16.Other Information

*Source:

Raw material MSDS

 

MSDS guideline (prepared by Japan Chemical Industry Association)

 

JIS* Z7150 Chemical Substance Material Safety Data Sheet

 

Liquefied Petroleum Gas MSDS

 

All material data covered by under Act on confirmation, etc. of Release Amounts of Specific Chemical Substances in the Environment and Promotion of Improvements to the Management There of (PRTR Law)

 

All material data covered by under Industrial Safety and Health Law

 

All material data covered by under Poisonous and Deleterious Substance Control Law (The Chemical Daily Co., Ltd.)

*JIS:

Japan Industrial Standard

    *Note:

This information may be revised based on new knowledge.

 

The information listed here does not guarantee the completeness or the accuracy of the information.
Since there are unknown hazards for all chemical products, the great care is required when handling them. Decision concerning the suitability of this product is to be made under the responsibility of the user.