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Material Safety Data Sheet

1.Chemical Product and Company Information


Shoe Waterproofing Spray 20 ml AWI-93


Air Water Sol Inc.


2-16-2 Iwamoto-cho, Kanda MC Bldg., Chiyoda-Ku Tokyo Japan (Main Office)
817-1 Sanga, Minori-cho, Ibaragi-gun, Ibaragi Japan  (Research Center)


Research and Development Dept.


03-5835-3900  (Main Office)   0299-48-4402  (Research Center)


03-5835-3908  (Main Office)   0299-48-4401  (Research Center)


In case of emergency, please call Research and Development Dept. at Research Center.

2.Composition/Information on Ingredients (a mixture)


CAS* No.


(Reg. No.)

(Weight %)

Fluorine resin



Not known





No. 518







Isoparaffine type carbon hydride Compound





Liquefied Petroleum Gas














No. 480


*CAS: Chemical Abstracts Service Registry Number
*PRTR: Pollutant Release & Transfer Register
*ISHL: Industrial Safety and Health Law

3.Summary of Toxicity and Hazards

Most Acute Toxicity & Hazards

*Combustible gas and liquid which burn extremely easily. Danger of possible explosion due to residual vapor.


*High pressured gas (combustible gas)
*Flammable liquid, Hazardous material


*Combustible gas inside. Danger of rupture due to rise in internal pressure caused by ignition or high temperature.


*Extremely combustible liquid. Danger of possible explosion due to residual gas.


*Can cause irritation to eyes, skin and respiratory tract. Can cause inflammation by the repeated contact,
*If ingested by an accident and enter into the lungs, there is a danger of lung damages.


*If the vapor is inhaled or the liquid is ingested, symptoms of dizziness or vomiting may occur.

4.First Aid Measures

Contact with Eyes

*Wash immediately for at least 15 minutes with a large amount of clean water. Alternatively, use boric acid solution and continue washing with clean water for a long period of time.


*Immediate treatment by a medical specialist.

Contact with Skin

*Quickly wipe the attached area with a cloth.


*Wash sufficiently with water, soap or a cleansing lotion for skin use.


  Do not use solvents or thinners.


*If an external change is noticed or there is pain, have a treatment by a medical specialist.


*When a large quantity of gas or vapor is inhaled, the affected person should be moved to a location with fresh air, keeping him warm and calm. If breathing is irregular or stops, conduct the artificial respiration.


*Do not let the affect person swallow vomit.


*If the person feel bad after inhaling gas, keep him calm in a place where there is fresh air and have him treated by a medical specialist.


*If ingested by a mistake, keep the person calm and have him treated by a Medical Specialist.
*Do not let him swallow vomit


*Do not let him cough excessively unless directed by a medical specialist.

5.Fire Fighting Measures

Extinguishing Media

*Type AB or BC powder fire extinguishers, Carbon dioxide, Foam or Sand

Extinguishing Methods

*Undertake the fire extinguishing from upwind. Those engaged in the fire extinguishing should wear suitable protective gears (fireproof clothing and eye protection) and use breathing apparatus.


*Quickly remove all combustible materials from the area.


*Used designated extinguishers.


*If aerosol containers are present, there is a danger of rupture. When engaged in the fire fighting, persons should keep a sufficient distance away, and containers exposed to heat should be cooled with water.

6.Accidental Release Measures


*To prevent exposure, proper protective gears should be worn during work.


*If leak occurs (a gush out), the measures are to be taken from upwind, and the leaking part of the container should be turned to upward ton let all gas gush out, before taking the measures.


*Sources of combustion and high temperature items in the vicinity should be removed immediately, and people should take refuge upwind.


Only authorized personnel are allowed in the area.


*Suitable fire extinguishers should be prepared in case of a fire brake.
*If large amount of vapor arises, the generation of the vapor should be held down by spraying with water.


*The leaked liquid should not be discharged into the sewer or the gutter.
*The leaked liquid should be collected in a sealed container, and the residual liquid should be absorbed with sand or inert absorbent, and moved to a safe location.
*The leaked liquid should be collected using a device made of materials which will not generate sparks though an impact or static electricity.
*For small leakage, sand is to be spread to absorb the liquid or it should be collected using a complementary method.
*For large leakage, the flow should be stopped with sand and lead the liquid to a safe location for the collection.

7.Handling and Storage (work is to be conducted in accordance with the pertinent regulations)



Technical Measures

*When the product used, the wind should be blow behind the person using the product so that the product does not come in direct contact with the person.


*It should be handled in well ventilated areas.


*Fire, sparks and high temperature items are not allowed to be used in the vicinity.


*The product should not be sprayed in the direction of a fire.


*If placed in areas where the temperature rises high, there is a danger of container rupture.


*Suitable protective gears should be worn to prevent contact with skin, mucus or clothing, and inhalation or entering eyes.


*For work done in enclosed areas, the work should be done with the sufficient ventilator installed and the person should wear suitable protective gears.


*After handling, hands should be washed thoroughly, and if the product sticks to the clothing, the cloth should be changed.


*Measures are to be take against static electricity, and antistatic material should be used for clothes and work shoes.

Safe Handling Advice

*Work should be done while wearing protective gears to prevent exposure to leakage.
Avoid inhalation of vapor and contact with skin.





Suitable Storage

*Store in a place where children cannot reach.


*Avoid direct sunlight and provide good ventilation.


*Because of a possibility of leak or gush out due to corrosion of the container, avoid storing in humid places such as kitchen and bathroom.


*Store away from fire or source of heat.


*Do not store in areas where the temperature rises above 40℃.


*Fire regulations, labor & health regulations and other regulations should be observed.

8.Exposure Control and Personal Protection

Place of Use

*There should be no source of high temperature or fire near by to where the product is used.


*When work is carried out in enclosed areas, a ventilator should also be used.


*A shower and an eye washing fountain should be installed in the facility where the work is carried out and they should be clearly marked its location.

Name of Material

Controlled Concentration (ppm)

ACGIH (ppm)

ACGIH (mg/m3)

Fluorine resin








Liquid Petroleum Gas

Not established

Not established

Not established





Protective Gears



*Antitoxin for organic gas, anti-dust mask, air mask for use in enclosed areas


*Gloves made of material which does not permit penetration of organic solutions and chemicals.


*Protective glasses

Skin and Body

*Working clothes, safety work shoes

Suitable Hygienic Practices

*No smoking, eating and drinking while working.

9.Physical and Chemical Properties

Physical State

Main Ingredient

Liquefied Petroleum Gas



Gaseous state under normal pressure, Liquid state in a pressurized container


No color, transparent

No color, transparent


Unique odor


Specific temperature or temperature range whereby the physical state changes.

Boiling Point / Range



Flash Point / Range



Ignition Point / Range



Vapor Pressure


0.22MPa (25℃)


0.69 (20℃)

0.56 (20℃)


Not dissolve in water

Dissolves slightly in water

10.Stability and Reactivity


*When the temperature reaching above 40℃, there is a danger of rupture.


*Pressure in a container at room temperature is about 0.20MPa.

Conditions to Avoid

*Storage in areas of high temperatures or humidity or use near fire.

Hazardous Decomposition Products

*A byproduct may arise from thermal decomposition of the fluorine resin.
The established values for this as follows:
Hydrogen fluoride: ACGIH YLV TWA 3 ppm
Carbonyl fluoride: ACGIH YLV TWA 2 ppm

11.Toxicological Information



Skin irritation:

Inflammation of the skin may occur as a result of drying of the skin or degrease.

Irritation (skin, eyes):

Skin/ can cause irritation.
Eyes/ can cause irritation and may lead to conjunctivitis.

Acute toxicity:

If ingested, it could be absorbed by the lungs and may be a danger of developing chemical-caused pneumonia.


The central nerve system, kidneys and lings could be affected.


With high density, there may be a lessening of consciousness.

Chronic toxicity:

Skin inflammation may result with repeated or prolonged contact with the skin.


The peripheral nerve system could be affected, and multiple nerve disorders could develop.

Sensitizing potential:

No information concerning sensitizing potential.

Source of cancer:

No information concerning cancer potential.

Reproductive toxicity:

No information concerning reproductive toxicity.


No information concerning teratogenesis.



*Liquefied Petroleum Gas

As of this time, there is no specific information regarding hazards.


*Product Hazard:

No tests are being conducted concerning safety as a product.

12.Ecological Information




Good dissolubility.


No reports regarding accumulative ability.

   Fish Toxicity:

It appears to have effects on fish in particular, therefore; it should not be discharged into the environment (sewerage, etc.).

   Ocatanol Water-Partition Coefficient:

log Pow 3.9 (ICSC)

*Liquefied Petroleum Gas

   Low pollutant fuel.

13.Disposal Considerations


*When disposing, the gas should be discharged completely before the handling.

Residual Waste

*The liquid remain after the safe discharge of the gas should be entrusted to authorized disposal companies, or;


make a hole in the container and let the liquid absorbed in diatom earth and burn the earth up in an open type incinerator little by little. When incinerated, the product generates a toxic gas. Thus, do not use an incinerator which does not have a toxic gas cleaning apparatus.


*Waste water used to wash the container and mechanical equipment should not be allowed to flow on the ground surface or into gutters.

Contaminated Containers and Packing

*To be separately disposed of after the content has been completely used.

14.Transport Information

Specific Transportation Safety Measures

*When being transported, the container temperature should be maintained under 40℃, and the container should be loaded in the ways that there are no tumbling, no falling and no damages. Prevention of cargo collapse should be firmly undertaken.

Land Transport

*Transport in accordance with Fire Service Law and other regulations which regulate the land transportation.

Sea Transport

*Transport in accordance with Ship Safety Law.

Air Transport

*Transport in accordance with Civil Aeronautics Law.

UN Classification and
UN number

1959 (aerosol)  Class 3

15.Regulatory Information

High Pressure Gas Safety Law

:Not applicable (liquefied gas, combustible gas)

Ship Safety Law

:Hazardous materials (high pressured gas), medium flash point inflammable liquid

Civil Aeronautics Law

:High pressured gas, flammable liquid

Fire Service Law

:Hazardous type 4 class 1 petroleum, hazard level II

Industrial Safety and Health Law

:Combustible gas, flammable materials

Poisonous and Deleterious Substance Control Law

:Contains no designated substances.

16.Other Information


Isoparaffine type carbon hydride compound MSDS

Fluorine resin MSDS

n-hexane MSDS

Dimethyl-polysiloxane MSDS

All material data covered by under Act on confirmation, etc. of Release Amounts of Specific Chemical Substances in the Environment and Promotion of Improvements to the Management There of (PRTR Law) (The Chemical Daily Co., Ltd.)

All material data covered by under Industrial Safety and Health Law (The Chemical Daily Co., Ltd.)
All material data covered by under Poisonous and Deleterious Substance Control Law (The Chemical Daily Co., Ltd.)


This information may be revised based on new knowledge.

The information listed here does not guarantee the completeness or the accuracy of the information.
Since there are unknown hazards for all chemical products, great care is required when handling them. Decision concerning the suitability of this product is to be made under the responsibility of the user.