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Material Safety Data Sheet

1.Chemical Product and Company Information

Product      

Shoe Polish Spray 20 ml AWI-94

Company   

Air Water Sol Inc.

Address

2-16-2 Iwamoto-cho, Kanda MC Bldg., Chiyoda-ku Tokyo Japan  (Main Office)
817-1 Sanga, Minori-cho, Ibaragi-gun, Ibaragi Japan  (Research Center)

Department

Research and Development Dept.

Telephone

03-5835-3900  (Main Office)   0299-48-4402  (Research Center)

Fax

03-5835-3908  (Main Office)   0299-48-4401  (Research Center)

 

In case of emergency, please call Research and Development Dept. at Research Center


2.Composition/Information on Ingredients (a mixture, listed hazardous and toxic substances)

Ingredients

CAS* No.

PRTR*

Gov. Reference No.
(JCSCL & ISHL)*

Content
(Weight %)

Non-ionized emulsifier (ethyl type)

9005-00-9

NA

(7)-97

1.0~1.5

ETA soap

8052-48-0

NA

--

1.0~2.0

Mineral turpentine

64742-96-7

NA

549

1.5~2.0

Wax

8001-750

NA

8-414

2.5~3.5

Preservative, fungicide

26172-55-4

NA

9-378

0.1~0.2

Silicon oil

555-67-2

NA

(7)-475

2.5~3.5

Fragrance

--

NA

--

0.1~0.2

Distilled water

7732-18-5

NA

--

35~40

Propane

74-98-6

NA

NA

As Liquefied Petroleum Gas 30~40

i-butane

75-28-5

NA

2-4

n-butane

106-97-8

NA

NA

*CAS: Chemical Abstracts Service Registry Number
*PRTR: Pollutant Release & Transfer Register
*JCSCL: Japanese Chemical Substances Control Law
*ISHL: Industrial Safety and Health Law


3.Summary of Toxicity and Hazards

Classification

*High pressured gas (combustible gas)

Most Acute Toxicity & Hazards

*Contains combustible gas. Danger of rupture due to rise in internal pressure caused by ignition or high temperature. The inhaling of highly concentrated gas causes anesthesia and there is a possible danger of addiction.

About Liquid

*In an aerosol, the emulsifier becomes foam and it makes difficult to ingest even if it is sprayed directly into the mouth. Also the distinct bad-taste makes it difficult to ingest.
If inadvertently ingested, emergency measures should be taken.


4.First Aid Measures

Contact with Eyes

*Wash immediately for at least 15 minutes with a large amount of clean water. Alternatively, use boric acid solution and continue washing with clean water for a long period of time.

 

*Immediate treatment by a medical specialist.

Contact with Skin

*Quickly wipe the attached area with a cloth.

 

*Wash sufficiently with water. Use soap or a cleansing lotion to wash the skin.

 

  Do not use solvents or thinners.

Inhalation

*When a large quantity of gas or vapor is inhaled, the affected person should be moved to a location with fresh air, keeping him warm and calm. If breathing is irregular or stops, conduct the artificial respiration.

 

*Do not let the affect person swallow vomit.

 

*Immediate treatment by a medical specialist.

Ingestion

*First, substances inside the mouth should be wiped and rinsed the mouth with cold or warm water. The person should be immediately examined by a medical specialist.

5.Fire Fighting Measures

Extinguishing Media

*Type AB or BC powder fire extinguishers

Extinguishing Methods

*Undertake the fire extinguishing from upwind. Those engaged in the fire extinguishing should wear suitable protective gears, (fireproof clothing and eye protection) and use breathing apparatus.

 

*Quickly remove all combustible materials from the area.

 

*Used designated extinguishers.

 

*If aerosol containers are present, there is a danger of rupture. When engaged in fire fighting, persons should keep a sufficient distance away, and containers exposed to heat should be cooled with water.


6.Accidental Release Measures

*To prevent exposure, proper protective gears (gloves, protective mask, apron, goggle, etc.) should be worn during work.

*If leak occurs (a gush out), the measures should be taken from upwind, and the leaking part of the container should be turned to upward to let all gas gush out, before taking the measures.

*Sources of combustion and high temperature items in the vicinity should be removed immediately, and people should take refuge upwind.

*Suitable fire extinguishers should be prepared in case of a fire brake.

*In case of leakage, use a collection device made of material which will not generate sparks though an impact or static electricity.
*if the leak amount is small, use dried sand, sawdust or waste cloth to absorb the liquid and collect into a container which can be sealed.
*If the leak amount is large, the spread of flow should be prevented by surrounding it with earth and leading the flow to a safe location for safe handling.
*The waste material should be treated in accordance with the relevant regulations. 


7.Handling and Storage (work is to be conducted in accordance with the pertinent regulations)

Handling

*When the product used, the wind should be blow behind the person using the product so that the product does not come in direct contact with the person.

 

*It should be handled in well ventilated areas.

 

*Fire, sparks, and high temperature items are not allowed to be used in the vicinity.

 

*It should not be sprayed in the direction of a fire.

 

*If placed in areas where the temperature rises high, there is a danger of container rupture.

 

*Suitable protective gears should be worn to prevent contact with skin, mucus or clothing, and inhalation or entering eyes.

 

*For work in enclosed areas, the work should be done with the sufficient ventilator should be installed and the person should wear suitable protective gears.

 

*After handling, hands should be washed thoroughly, and if the product sticks to the clothing, the cloth should be changed.

 

*Measures are to be take against static electricity and antistatic material should be used for clothes and work shoes.

 

 

Storage

*Store in a place where children cannot reach.

 

*Avoid direct sunlight and provide good ventilation.

 

*Store with a sign indicating a hazardous substance.

 

*Because of a possibility of leak or gush out due to corrosion of the container, avoid storing in humid places, such as kitchen and bathroom.

 

*Store away from fire or source of heat.

 

*Do not store in areas where the temperature rises above 40℃.

 

*Electrical equipment used in the storage areas should be explosion-proof structure and the equipment should be properly grounded.

 

*Avoid contact with strong oxidation agent, hydrogen peroxide, chromic acid and bromine.


8.Exposure Control and Personal Protection

Allowable Exposure Concentration

Ingredients

Japan Society of Occupational Health

ACGIH

IARC

Other Hazards

Liquefied Petroleum Gas

1,000 ppm

1,800 ppm

No data

--

Non-ionized emulsifier (ethyl type)

No data

No data

No data

LD50/kg 2.0

ETA soap

No data

No data

No data

LD50/kg 3.0

Mineral turpentine

No data

No data

No data

LD50/kg 5.0

Wax

No data

No data

No data

LD50/kg 5.4

Preservative, Fungicide

No data

No data

No data

--

Silicon oil

No data

No data

No data

--

Fragrance

No data

No data

No data

LD50/kg 5.0

Distilled water

--

--

--

--


Place of Use

*There should be no sources of high temperature or fire near to where the product is used, and the explosion prevention measure should be employed.
*When work is carried out in enclosed areas, a ventilator should also be used.

 

*A shower and an eye washing fountain should be installed in the facility where the work is carried out and they should be clearly marked its location.

Protective Gears

 

Eyes Protection

*Protective glassed should be worn.

Skin Protection

*Gloves made of material which does not permit penetration of organic solutions and chemicals.

Breathing Protection

*Antitoxin masks for organic gas or anti-dust masks should be worn. Use air masks in enclosed areas.

Other Protection

*Non permeable protective gears, such as aprons and protective clothing, should be worn in accordance with the type of work.


9.Physical and Chemical Properties

Physical State

Main Ingredient

Liquefied Petroleum Gas

State

Liquid

Gaseous state under normal pressure, Liquid state in a pressurized container

Color

Milky white

No color, transparent

Odor

Floral bouquet odor

Odorless

Specific temperature or temperature range whereby the physical state changes.

Boiling Point / Range

92℃

-42.1~-0.5℃

Vapor Pressure

No data

0.278~1.275MPa (20℃)

Specific Gravity

0.914 (20℃)

0.555 (20℃)

pH

8.87 (20℃)

--

Flash Point / Range

               --

-104.4~-73.8℃

Ignition Point / Range

No data

405~550℃

Explosion Limit

No data

1.8~9.5 vol.%

Combustibility

Yes

Yes

Ignitability (natural ignitability, reaction to water)

None

None

Oxidation ability

None

None

Self-Reactivity & Explosiveness

None

None

Stability & Reactivity

Stable

Stable

Others

--

No useful data

10.Stability and Reactivity (as a product)

*When the temperature reaching above 40℃, there is a danger of container rupture.

*Pressure in a container at room temperature of 25℃ is 0.45MPa.

*Stable under normal conditions.


11.Toxicological Information (on the ingredient. The information includes human symptoms and
         pathological information.)

Skin corrosiveness

: No data

Irritation (skin, eyes)

: No data

Sensitizing potential

: No data

Acute toxicity

: No data

Semi-acute toxicity

: No data

Chronic toxicity

: No data

Source of Cancer

: No data

Source of Mutation

: No data

Reproductive toxicity

: No data

Teratogenesis

: No data

Others (including generation of toxic gas in reaction with water.)

: No significant information

Irritation of the stomach, vomiting, or diarrhea may result if the crude liquid is ingested. Feelings of illness may result if the mist is inhaled.


12.Ecological Information

When leakage occurs or when disposing the product, care should be taken as there may be effects on the environment.


13.Disposal Considerations

The user may dispose the product as an industrial waste itself or may entrust to an industrial waste disposal company approved by the local authority. When a local public organization undertakes such disposal, the user may entrust disposal to it.


14.Transport Information (The items listed in 7. Handling and Storage section should be observed.)

When being transported, the container temperature should be maintained under 40℃, and the container should be loaded in the ways that there are no tumbling, no falling and no damaging. Prevention of cargo collapse should be firmly undertaken.

 

 

Land Transport

*Transport in accordance with Fire Service Law and other local regulations.

Sea Transport

*Transport in accordance with Ship Safety Law.

Air Transport

*Transport in accordance with Civil Aeronautics Law.

Regulations for the Carriage and Storage of Dangerous Goods in Ships

IMDG Code Class 2 (UN No. 1950)


15.Regulatory Information

High Pressure Gas Safety Law

: Not applicable (liquefied gas, combustible gas)

Fir Service Law

: Non hazardous material

Ship Safety Law

: Hazardous materials (high pressured gas)

Civil Aeronautics Law

: High pressured gas

PRTR

: Not applicable

Industrial Safety and Health Law

: Reporting required substance (Butane) according to Article 57, Section 2-1.


16.Other Information

*Source:

Ethanol MSDS

Liquefied Petroleum Gas MSDS

All material data covered by under Industrial Safety and Health Law (The Chemical Daily Co., Ltd.)

All material data covered by under Act on confirmation, etc. of Release Amounts of Specific Chemical Substances in the Environment and Promotion of Improvements to the Management There of (PRTR Law) (The Chemical Daily Co., Ltd.)

Home page of National Institutes of Technology and Evaluation


*Note:

This information may be revised based on new knowledge.

The information listed here does not guarantee the completeness or the accuracy of the information.
Since there are unknown hazards for all chemical products, great care is required when handling them. Decision concerning the suitability of this product is to be made under the responsibility of the user.