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Material Safety Data Sheet

1.Chemical Product and Company Information

Product      

Style-rich Luster Hair Spray NET 12g AWI-99

Company   

Air Water Sol Inc.

Address

2-16-2 Iwamoto-cho, Kanda MC Bldg., Chiyoda-ku Tokyo Japan  (Main Office)
817-1 Sanga, Minori-cho, Ibaragi-gun, Ibaragi Japan  (Research Center)

Department

Research and Development Dept.

Telephone

03-5835-3900  (Main Office)   0299-48-4402  (Research Center)

Fax

03-5835-3908  (Main Office)   0299-48-4401  (Research Center)

 

In case of emergency, call Research and Development Dept. at Research Center. Product Code: AH00716


2.Composition/Information on Ingredients (a mixture)

Ingredients
(General names)

CAS* No.

PRTR*

ISHL*
(Reg. No.)

Content (Weight %)

Silicone

Trade Secret

NA

NA

22~32

Dimethl polysiloxane

63148-62-9

NA

NA

Less than 2

Caprylic triglyceride

65381-09-1

NA

NA

Less than 1

Rosa canina fruit oil (linoleic acid and linolenic acid as main ingredients)

84603-93-0

NA

NA

Less than 1

Simmondsia chinensis (Jojoba) seed consists of high-grade unsaturated fatty alcohol and high-grade unsaturated fatty acid

61789-91-1

NA

NA

Less than 1

Other ingredients

 

 

 

Less than 2

Liquefied Petroleum Gas

Propane

74-98-6

NA

NA

69~74

i-butane

75-28-5

NA

NA

n-butane

106-97-8

NA

№ 480

*CAS: Chemical Abstracts Service Registry Number
*PRTR: Pollutant Release & Transfer Register
*ISHL: Industrial Safety and Health Law


3.Summary of Toxicity and Hazards

Classification

*High pressured gas (combustible gas)

Danger

*Contains combustible gas. Danger of rupture due to rise in internal pressure caused by ignition or high temperature.

Toxicity

*There is a danger of frostbite if direct contact occurs with liquid state of the gas.


4.First Aid Measures

In all of the following cases, there should be an examination by a medical specialist as required.

Contact with Eyes

*Wash immediately for at least 15 minutes with a large amount of clean water.
*Immediate treatment by a medical specialist.

Contact with Skin

*If liquid state of the gas comes in contact with skin, make a treatment for frostbite.

 

*If an external change is noticed or there is pain, have a treatment by a medical specialist.

Inhalation

*If large quantity of gas is inhaled, measures for dealing with oxygen deficiency should be taken.

 

*Immediate treatment by a medical specialist, as required.

Ingestion

*Immediate treatment by a medical specialist, as required.

5.Fire Fighting Measures

Extinguishing Media

*Mist water, type ABC or BC powder fire extinguishers, Carbon dioxide or Foam

 

*Do not use a rod shaped spray of water.

Extinguishing Methods

*Under take the fire extinguishing from upwind . Those engaged in the fire extinguishing should wear suitable protective gears (heat resistant clothing, protective glasses, etc.) and breathing apparatus.

 

*Quickly remove all combustible materials from the area.

 

*Used designated extinguishers.
*Unauthorized persons should not be allowed in the fire area.
*Peripheral equipment should be cooled with water spray.

 

*If aerosol containers are present, there is a danger of rupture. When engaged in the fire extinguishing, persons should keep a sufficient distance away and containers exposed to heat should be cooled with water.


6.Accidental Release Measures

Personal Precautions

*To prevent exposure, proper protective gears should be worn during work.
*Avoid contact of the liquid with the eyes, inhalation of the vapor and ingestion of the liquid.

Environment Precautions and Removal Methods

*If leak occurs, sand or earth should be used to prevent the liquid flow on the ground or into the gutter, water ways or rivers.
*If leak occurs (a gush out), the measures are to be taken from upwind and the leaking part of the container should be turn to upward to let all gas gush out before the handling.

 

*Sources of combustion and high temperature items in the vicinity should be removed immediately, and people should take refuge upwind.

 

*Only authorized personnel should be allowed in the areas.

 

*Suitable fire extinguishers should be prepared in case of a fire break.

 

*Whether seal the leaked area or evacuate people from the area should be decided according to a local emergency evacuation regulation.

 

*Do refer to all information in MSDS of the product for personnel protective gears.

 

*If the leaked liquid is collectable, collect the liquid in a suitable container and store in a safe place.

 

*Use a suitable absorbent to remove the liquid. If liquid leaked on floor, it may make the floor slippery even with a small amount. There remove the liquid completely with suitable method.

 

*To finish the removal work, detergent, solvent or high-pressured steam maybe effective.

 

*Since there may be a possibility of natural generation of heat, suitable disposal of the removed liquid or waste is required.

 

*The disposal or discharge of the product may be subject to laws or local regulations. At the same time, equipment or devices used to clean or collect the product may also be subject to laws and local regulations. It is necessary to check which laws and local regulations should be followed when the product is disposed or discharged.


7.Handling and Storage (work is to be conducted in accordance with the pertinent regulations)

Handling

 

Technical Measures

*When the product id used, the wind should be blow behind the person using the product so that the product does not come in direct contact with the person.

 

*It should be handled in well ventilated areas.

 

*Fire, sparks and high temperature items are not allowed to be used in the vicinity.

 

*Prevent generation of sparks, static electricity or fire.

 

*The product should not be sprayed in the direction of a fire.

 

*If placed in areas where the temperature rises high, there is a danger of container rupture.

Precautions

*For used in enclosed areas, a sufficient ventilator should also be used.

 

*After the use, hands should be washed thoroughly.

 

*Measures are to be taken against static electricity and anti-static material should be use for working clothes and shoes.

Safety Precaution

*Avoid prolonged or repeated contact with eyes and skin.

 

*Suitable protective gears should be used to avoid the product contact with skin or mucous as well as with clothing and inhalation and entering eyes.  Hands should be washed after using the product.

Storage

 

Suitable Storage

*Store in a place where children cannot reach.

Conditions

*Avoid direct sunlight and provide good ventilation.

 

*Because of a possibility of leak or gush out due to corrosion of the container, avoid storing in humid places such as kitchen and bathroom.

 

*Store away from fire or source of heat.

 

*Do not store in areas where the temperature rises above 40℃.

 

*Fire regulations and labor & health regulations and other regulations should be observed.


8.Exposure Control and Personal Protection Measures

Place of Use

*There should be no source of high temperature or fire near by to where the product is used.

 

*Use a common or a localized ventilator to provide suitable ventilation in the use areas

 

*Provide a washing equipment for eyes or body near the use areas.


Name of Material

Controlled
Concentration (ppm)

Japan Industrial Health Association

ACGIH (TLV)

Silicone

Not established

Not established

Not established

Dimethl polysiloxane

Not established

Not established

Not established

Caprylic triglyceride

Not established

Not established

Not established

Rosa canina fruit oil (linoleic acid and linolenic acid as main ingredients)

Not established

Not established

Not established

Simmondsia chinensis (Jojoba) seed consists of unsaturated fatty alcohol and unsaturated fatty acid

Not established

Not established

Not established

Propane

Not established

2,500 ppm

2,500 ppm

i-butane

Not established

Not established

Not established

n-butane

Not established

800 ppm

800 ppm


Protective Gears

 

Breathing
Hands
Eyes
Skin and Body
Suitable Hygienic Practice

*Use a suitable protective apparatus.
*Nothing needed in particular.
*Safety glasses
*Wash hands after use.
*No smoking, eating and drinking with in use.
Also, wash hands after use (especially before meal or smoking).


9.Physical and Chemical Properties

Physical State

Main Ingredient

Liquefied Petroleum Gas

State

Liquid

Gaseous state under normal pressure, Liquid state in a pressurized container

Color

No color, transparent

No color, transparent

Odor

Odorless

Odorless

Specific temperature/temperature range whereby the physical state changes.

Boiling Point / Range

No data

-42.1~-0.5℃

Flash Point / Range

NA

-104.4~-73.8℃

Ignition Point / Range

NA

405~550℃

Vapor Pressure / Range

NA

1.275~0.278 (20℃)

Density

0.961 (25℃)

0.568 MPa (20℃)

pH

NA

NA

Explosive Limit

No data

1.8~9.5 vol. %

Solubility

Difficult to dissolves in water

Dissolves slightly in water

10.Stability and Reactivity

Stability

*When the temperature reaching above 40℃, there is a danger of rupture.

 

*Pressure in a container at room temperature is about 0.5MPa.

Conditions to Avoid

*Storage in areas of high temperature and humidity or use near fire.
*The liquid content may react with strong oxidation agents.

Hazardous Decomposition Products

*Silica gel, carbon oxides and small amounts of hydrocarbon from imperfect combustion.


11.Toxicological Information

*Silicone

 

Sensitizing potential

: None in particular.

Acute toxicity

: Oral intake in rats > LD50 >20g/kg

Local effects

: Eyes  With direct contact, there may be temporary redness and a feeling of discomfort

 

: Skin   In a single and short period of exposure, no major effects are expected.

Acute exposure effects

: Ingestion  Under normal use, toxicity is low from ingestion.

 

: Inhalation  In a single and short period of exposure, no major effects are expected.

Chronic & Protracted

: Skin       The effects are not known.

toxicity

: Ingestion   Repeated oral intake or large amount of intake, there may be cases of body injury.

 

: Inhalation  The effects are not known.

Source of Cancer

: None in particular.

Source of Mutation

: None in particular.

Reproductive toxicity

: None in particular.

Teratogenesis

: None in particular.

Others

: None in particular.

 

 

*Liquefied Petroleum Gas

As of this time, there are no reports of toxic properties. However, a label on a container used for a single gas burner or on a portable gas lighter warms that “Liquefied Petroleum Gas should only be used as fuel and should never be inhaled.”

 

*Product Hazard

: No tests are being conducted concerning safety as a product.


12.Ecological Information

*When there is leakage or disposing the product, care should be taken as there may be effects on the environment.

*Content (as Silicone)

 

Move or Distribution in Environment

: Low boiling point siloxane dissolves in extremely small amount in water and evaporates when exposed to air. Low boiling point siloxane in the air reacts with hydroxyl radicals and dissolves preferentially over most other chemical substances exist in the environment. Low boiling point siloxane in soil is removed by compound effects of volatilization, hydrolysis, and clay catalysts.

Effects on Environment

: No harmful effects on aquatic life.

Bio-accumulation Potential

: Under the natural environmental conditions, there are no representative values of bio-accumulation of volatile low molecule siloxane in fish. There are however, some observed incidents in limited conditions.

Effects under Waste Water Treatment

: There are no ill effects forecasted on bacteria. The siloxane contained in the product does not contribute to BOD. Low boiling point siloxane is effectively removed with the same amount of gas and sludge (>90%). The residual low boiling point siloxane exists in the treated water as granular form as they are hard to dissolve in water.

 

 

*Propellant

: Liquefied Petroleum Gas is a low pollutant fuel.


13.Disposal Considerations

When disposing, the gas should first be completely discharged before handling.

Residual Waste

*The liquid remain after the safe discharge of gas, is equivalent to an industrial waste (waste oil) under Waste Disposal and Public Cleaning Law.

Contaminated Container and Packaging

*To be separately disposed of after the content have been completely used.

 

 

*When disposing the product, in addition to following Waste Disposal and Public Cleaning Law, local regulations should be followed as well.


14.Transport Information

Specific Transport Safety Measures

*When being transported, the container temperature should be maintained under 40℃, and the container should be loaded in the ways that there are no tumbling, no falling and no damaging. Prevention of cargo collapse should also be firmly undertaken.

Land transport

*Transport in accordance with Fire Service Law and other regulations.

Sea transport

*Transport in accordance with Ship Safety Law.

Air Transport

*Transport in accordance with Civil Aeronautics Law.


15.Regulatory Information

High Pressure Gas Safety Law

: Not applicable (liquefied gas, combustible gas)

Ship Safety Law

: Hazardous material (high pressured gas)

Civil Aeronautics Law

: High pressured gas

Fire Service Law

: Type 4 class 3 petroleum

Industrial Safety and Health Law

: Combustible gas,

Regulations for the Carriage and Storage of Dangerous Goods in Ships

: IMDG code class 2.1 (UN No.1950)

Poisonous and Deleterious Substance Control Law

: Contains no designated substances.


16.Other Information

Liquefied Petroleum Gas MSDS

Raw material MSDS

All material data covered by under Industrial Safety and Health Law

All material data covered by under Act on confirmation, etc. of Release Amounts of Specific Chemical Substances in the Environment and Promotion of Improvements to the Management There of (PRTR Law)

All material data covered by under Poisonous and Deleterious Substance Control Law (Chemical Daily Co., Ltd.)


Note:

This information may be revised based on new knowledge.

The information listed here does not guarantee the completeness or the accuracy of the information.
Since there are unknown hazards for all chemical products, the great care is required when handling them. Decision concerning the suitability of this product is to be made under the responsibility of the user.